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2 article(s) from Wang, Hai Ming

Topochemical control of the photodimerization of aromatic compounds by γ-cyclodextrin thioethers in aqueous solution

Hai Ming Wang and
Gerhard Wenz

Beilstein J. Org. Chem. 2013, 9, 1858–1866, doi:10.3762/bjoc.9.217

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Figure 1: Chemical structures of selected aromatic guests: anthracene, ANT; acenaphthylene, ACE; and coumarin...

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Figure 2: Structures of γ-CD and γ-CD thioethers 1–7.

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Scheme 1: Photodimerization of ACE.

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Figure 3: ¹H NMR spectrum of the photo product of ACE in the presence of γ-CD thioether 3 in CDCl₃.

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Figure 4: Schematic drawing of the ACE photodimers in γ-CD: a) the syn photodimer and b) the anti photodimer....

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Figure 5: Structures of COU photodimers.

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Figure 6: Partial ¹H NMR of the photodimers formed after irradiation of COU at various concentrations of Na₂SO...

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Published 12 Sep 2013

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Molecular solubilization of fullerene C₆₀ in water by γ-cyclodextrin thioethers

Hai Ming Wang and
Gerhard Wenz

Beilstein J. Org. Chem. 2012, 8, 1644–1651, doi:10.3762/bjoc.8.188

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Figure 1: Space-filling model of the most stable complex between γ-CD and C₆₀ with 1:2 stoichiometry, calcula...

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Scheme 1: Chemical structures of γ-CD and γ-CD thioether 1–7 used to solubilize C₆₀ in water.

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Figure 2: UV–vis spectra of (a) C₆₀ solution in THF, (b) aqueous solutions of C₆₀ with 6 mM γ-CD thioether 5 ...

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Figure 3: Isothermal kinetics of the dissolution of C₆₀ in the presence of 10 mM CD 7 in water. Curve: best f...

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Scheme 2: Mechanistic description of the two possible mechanisms for the complexation of C₆₀ (G) by CD hosts,...

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Figure 4: Phase-solubility diagram of C₆₀ in aqueous solution in the presence of CD 3.

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Figure 5: UV–vis spectra of the water solution of C₆₀ produced by stirring C₆₀ in 6mM γ-CD solution in DMF/to...

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Figure 6: Size distribution of the molecular solution of C₆₀ with 6 mM CD 5 in water at 25.0 °C: before centr...

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Figure 7: Size distributions of the aqueous C₆₀ dispersions after filtration, produced by stirring C₆₀ in 6mM...

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Published 28 Sep 2012

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Topochemical control of the photodimerization of aromatic compounds by γ-cyclodextrin thioethers in aqueous solution

Molecular solubilization of fullerene C60 in water by γ-cyclodextrin thioethers

Molecular solubilization of fullerene C₆₀ in water by γ-cyclodextrin thioethers